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In the presence of moderately strong acids in MeCN, Co complexes with BF2-bridged diglyoxime ligands are active catalysts for the redn. of protons to H2 at potentials as pos. as -0.28 V vs. SCE. [on SciFinder (R)] ...
In this paper we address the problem of detection and tracking of pedestrians in complex scenarios. The inclusion of prior knowledge is more and more crucial in scene analysis to guarantee flexibility and robustness, necessary to have reliability in comple ...
The trinuclear Ru complexes [RuCl2(PAd2Bu)]3 (1) and [RuCl2(PtBu2Cy)]3 (2) were obtained by reaction of [(p-cymene)RuCl2]2 with 2 equiv of the resp. sterically demanding phosphine. Crystallog. analyses of 1 and 2 show that the three metal fragments are con ...
Three immobilized Cu(II) complexes were generated by the following: (a) homopolymerization of the N,N',N '' chelate ligand tris[2-(1-vinylimidazolyl)]phosphine (1) and subsequent metalation with CuCl2; (b) copolymerization of 1 with ethyleneglycol dimethac ...
We prove that for all local fields SLn is stable over n in terms of continuous bounded cohomology. We complement this by various computations in low degree, showing notably the vanishing of the third bounded cohomology of SLn(R) for all n. We link the corr ...
With a view to develop drugs that could resist hydrolysis in aq. media,organometallic arene-capped ruthenium(II) 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (RAPTA) complexes bearing chelating carboxylate ligands have been prepd. and studied. The new com ...
We introduce new techniques to extend superrigidity theory beyond the scope of Lie or algebraic groups. We construct a cohomological invariant which accounts for, and generalizes, all known superrigidity results for actions on negatively curved spaces. Tog ...
A facile pathway to [RuCl2(η6-benzocrownether)]2 complexes is described and crystal structures of the complexes [RuCl2(η6-benzo-15-crown-5)]2 and [RuCl2(η6- ...
Direct reaction between [Cr(CO)6] and arenes with ionic substituents affords the corresponding arene-chromium tricarbonyl complexes, [Cr(CO)3(arene)], in only modest yield. In contrast, these complexes can be prepared in pure form in ...
Highly reactive tris-carbene Co(I) complexes [(TIMENaryl)Co]Cl react with org. azides to yield monomeric Co(III) imido complexes (TIMENaryl)Co(NAr') (aryl = mes, xyl; Ar = -C6H4-CH3, -C6H4-OCH3). The cobalt-imido fragment in these complexes is elec ...