Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of 1000 K (727 °C); other alloys of steel have different eutectoid temperatures. The austenite allotrope is named after Sir William Chandler Roberts-Austen (1843–1902); it exists at room temperature in some stainless steels due to the presence of nickel stabilizing the austenite at lower temperatures. From alpha iron undergoes a phase transition from body-centered cubic (BCC) to the face-centered cubic (FCC) configuration of gamma iron, also called austenite. This is similarly soft and ductile but can dissolve considerably more carbon (as much as 2.03% by mass at ). This gamma form of iron is present in the most commonly used type of stainless steel for making hospital and food-service equipment. Austenitization means to heat the iron, iron-based metal, or steel to a temperature at which it changes crystal structure from ferrite to austenite. The more-open structure of the austenite is then able to absorb carbon from the iron-carbides in carbon steel. An incomplete initial austenitization can leave undissolved carbides in the matrix. For some iron metals, iron-based metals, and steels, the presence of carbides may occur during the austenitization step. The term commonly used for this is two-phase austenitization. Austempering Austempering is a hardening process that is used on iron-based metals to promote better mechanical properties. The metal is heated into the austenite region of the iron-cementite phase diagram and then quenched in a salt bath or other heat extraction medium that is between temperatures of . The metal is annealed in this temperature range until the austenite turns to bainite or ausferrite (bainitic ferrite + high-carbon austenite). By changing the temperature for austenitization, the austempering process can yield different and desired microstructures.

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