Concept
The phlogiston theory is a superseded scientific theory that postulated the existence of a fire-like element called phlogiston (flɒˈdʒɪstən,floʊ-,-ɒn) contained within combustible bodies and released during combustion. The name comes from the Ancient Greek φλογιστόν phlogistón (burning up), from φλόξ phlóx (flame). The idea was first proposed in 1667 by Johann Joachim Becher and later put together more formally by Georg Ernst Stahl. Phlogiston theory attempted to explain chemical processes such as combustion and rusting, now collectively known as oxidation. It was challenged by the concomitant weight increase and was abandoned before the end of the 18th century following experiments by Antoine Lavoisier and others. Phlogiston theory led to experiments that ultimately concluded with the discovery of oxygen. Phlogiston theory states that phlogisticated substances contain phlogiston and that they dephlogisticate when burned, releasing stored phlogiston which is absorbed by the air. Growing plants then absorb this phlogiston, which is why air does not spontaneously combust and also why plant matter burns as well as it does. Thus phlogiston accounted for combustion via a process that was the inverse of that of the oxygen theory. In general, substances that burned in the air were said to be rich in phlogiston; the fact that combustion soon ceased in an enclosed space was taken as clear-cut evidence that air had the capacity to absorb only a finite amount of phlogiston. When the air had become completely phlogisticated it would no longer serve to support the combustion of any material, nor would a metal heated in it yield a calx; nor could phlogisticated air support life. Breathing was thought to take phlogiston out of the body. Joseph Black's Scottish student Daniel Rutherford discovered nitrogen in 1772, and the pair used the theory to explain his results. The residue of air left after burning, in fact, a mixture of nitrogen and carbon dioxide, was sometimes referred to as phlogisticated air, having taken up all of the phlogiston.
