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Publications associées (46)

Asymmetric Construction of α,α‐Disubstituted Piperazinones Enabled by Benzilic Amide Rearrangement

An unprecedent asymmetric catalytic benzilic amide rearrangement for the synthesis of α,α-disubstituted piperazinones is reported. The reaction proceeds via a domino [4+1] imidazolidination/formal 1,2-nitro- gen shift/1,2-aryl or alkyl migration sequence, ...

2023

Asymmetric Construction of alpha,alpha-Disubstituted Piperazinones Enabled by Benzilic Amide Rearrangement

Jieping Zhu, Hua Wu, Yuping He

An unprecedent asymmetric catalytic benzilic amide rearrangement for the synthesis of a,a-disubstituted piperazinones is reported. The reaction proceeds via a domino [4+1] imidazolidination/formal 1,2-nitrogen shift/1,2-aryl or alkyl migration sequence, em ...

WILEY-V C H VERLAG GMBH2023

Gemini: Elastic SNARKs for Diverse Environments

Alessandro Chiesa

We introduce a new class of succinct arguments, that we call elastic. Elastic SNARKs allow the prover to allocate different resources (such as memory and time) depending on the execution environment and the statement to prove. The resulting output is indep ...

SPRINGER INTERNATIONAL PUBLISHING AG2022

Miss-Optimized Memory Systems: Turning Thousands of Outstanding Misses into Reuse Opportunities

Mikhail Asiatici

Even if Dennard scaling came to an end fifteen years ago, Moore's law kept fueling an exponential growth in compute performance through increased parallelization. However, the performance of memory and, in particular, Dynamic Random Access Memory (DRAM), ...

EPFL2021

Micro-architectural Analysis of Database Workloads

Utku Sirin

Database workloads have significantly evolved in the past twenty years. Traditional database systems that are mainly used to serve Online Transactional Processing (OLTP) workloads evolved into specialized database systems that are optimized for particular ...

EPFL2021

Memory chip or memory array for wide-voltage range in-memory computing using bitline technology

David Atienza Alonso, Marina Zapater Sancho, Marco Antonio Rios, William Andrew Simon

A random access memory having a memory array having a plurality of local memory groups, each local memory group including a plurality of bitcells arranged in a bitcell column, a pair of local bitlines operatively connected to the plurality of bitcells, a p ...

2021

Square Attack: a query-efficient black-box adversarial attack via random search

Nicolas Henri Bernard Flammarion, Maksym Andriushchenko, Francesco Croce

We propose the Square Attack, a new score-based black-box

l_2

and

l_\infty

adversarial attack that does not rely on local gradient information and thus is not affected by gradient masking. The Square Attack is based on a randomized search scheme where ...

2020

Gain-Cell Embedded DRAMs: Modeling and Design Space

Andreas Peter Burg, Adam Shmuel Teman, Robert Giterman, Andrea Bonetti

Among the different types of dynamic random-access memories (DRAMs), gain-cell embedded DRAM (GC-eDRAM) is a compact, low-power, and CMOS-compatible alternative to conventional static random-access memory (SRAM). GC-eDRAM achieves high memory density, as i ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2020

Intermolecular Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes

Nicolai Cramer, Qui-Hien Nguyen

Atropisomeric (hetero)biaryls are motifs with increasing significance in ligands, natural products, and biologically active molecules. The straightforward construction of the stereogenic axis by efficient C-H functionalization methods is extremely rare and ...

2020

Improving Main-memory Database System Performance through Cooperative Multitasking

Georgios Psaropoulos

Database systems access memory either sequentially or randomly. Contrary to sequential access and despite the extensive efforts of computer architects, compiler writers, and system builders, random access to data larger than the processor cache has been s ...

EPFL2019

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Square Attack: a query-efficient black-box adversarial attack via random search

Nicolas Henri Bernard Flammarion, Maksym Andriushchenko, Francesco Croce

We propose the Square Attack, a new score-based black-box

l_2

and

l_\infty

adversarial attack that does not rely on local gradient information and thus is not affected by gradient masking. The Square Attack is based on a randomized search scheme where ...

2020