Mode normal | EPFL Graph Search

droite|vignette|248px|Visualisation d'un mode normal de vibration d'une peau de tambour, constitué d'une membrane circulaire souple attachée rigidement sur la totalité de ses bords. . Pour un système oscillatoire à plusieurs degrés de liberté, un mode normal ou mode propre d'oscillation est une forme spatiale selon laquelle un système excitable (micro ou macroscopique) peut osciller après avoir été perturbé au voisinage de son état d'équilibre ; une fréquence naturelle de vibration est alors associée à cette forme. Tout objet physique, comme une corde vibrante, un pont, un bâtiment ou encore une molécule possède un certain nombre, parfois infini, de modes normaux de vibration qui dépendent de sa structure, de ses constituants ainsi que des conditions aux limites qui lui sont imposées. Le nombre de modes normaux est égal à celui des degrés de liberté du système. Le mouvement le plus général d'un système est une superposition de modes normaux. Le terme « normal » indique que chacun de

Long Spin Lifetime in Rare-Earth Single-Atom Magnets at Surfaces

Boris Sorokin

Further miniaturisation of magnetic storage devices requires an advent of new types of magnets, since classical ferromagnetic materials show lack of remanence at nano- and subnanoscale. A single atom can represent the smallest possible bit of information. Even though the isolated single atoms are paramagnetic, the interaction of surface adsorbed atoms with a substrate can result in high magnetic anisotropy energy and long magnetisation lifetime. In this thesis the magnetic properties of surface supported rare-earth single atoms are investigated with X-ray absorption spectroscopy, X-ray magnetic circular dichroism and multiplet simulations. The first goal of the project was to find new adatom/substrate combinations that exhibit a long adatom magnetic lifetime, possibly extending the current limits of the atomic magnetic moment stability to higher temperatures and longer spin relaxation times. The second objective was to implement the external electric field control of the adatom magnetic properties.Firstly, we present the experimental and theoretical research on Dy and Ho single atoms deposited on BaO. A comparison of our results with similar studies sheds light on the impact of the substrate crystal field, in particular Dy-O bond covalency, on the magnetic stability of the rare-earth adatoms. Next, the detailed experimental investigation of Dy single atoms on ZnO is presented. This adatom/substrate pair is used as first attempt to implement the electric field control of the adatom magnetic properties. Lastly, we study the Dy adatoms on graphene layers grown on various metals. The vibrational modes of the metallic substrates are shown to strongly affect the Dy spin lifetime, while addition of a second graphene layer does not allow to significantly improve the adatom magnetic stability.

EPFL2022

Physics of optically driven nanojunctions

Philippe Andreas Rölli

Recent years have seen spectacular developments in the domain of nano-optics. Alongside the well-known techniques of super-resolution microscopy progress in nanofabrication has enabled important improvements in the fields of optical imaging and spectroscopy. Nowadays enhancements of specific near-field interactions by nano-antennae/cavities allows the optical readout of single molecule properties in a number of different systems. The observation of normal modes of vibration for example carries essential information on the orientation, link to the interface and environment in which the molecule is embedded. This thesis develops firstly a novel theoretical frame for these vibration-cavity interactions by following the optomechanical formalism, which has proven to be an accurate treatment of a wide variety of mechanical systems interacting with a laser field. By leveraging this framework, we investigate on the one hand several quantum limits. On the other hand, for the parameter space experimentally available and for well-designed cavities, novel regimes of interaction between the collective mode of vibration of an ensemble of molecules and an optical tone seem within reach. In parallel, this thesis experimentally explores one specific realization of such a system. In collaboration with the group of Christophe Galland we constructed the optical setups necessary to interrogate our nanostructures. The class of structures constructed, known as self-assembled nanojunctions or nanoparticles on mirror, reaches confinement of electric fields via plasmonic modes close to its fundamental limit and enables the study of many different mechanical systems whose thickness consist in a single molecule. Along this research we have developed techniques to characterize mechanical, electronic and thermal observables of nanojunctions interacting with an optical field. Our experimental study has enabled the discovery of a novel effect related to the electronic confinement of these quasi-0-dimensional structures. The characteristic photoluminescence of metallic nanostructures is found to consistently blink in nanojunctions akin to other quantum emitters. The mechanisms explaining in detail this blinking remain debatable but the numerous experimental data collected highlight the key role of the interface in the specificities of the blinking observed. This finding opens novel ways to characterize the important and to date ill-described question of the interfaces in nanojunctions. The observed modifications of the nanojunctions optical properties might constitute an interesting step towards the development of a novel class of functional materials ('gap-materials') with enhanced and tailored electro-optical properties. The last part of this thesis considers one technological application for this class of material by conceptually developing a new kind of detector based on the upconversion of an infrared photon to the visible; exploiting thus in a unique way the optical properties of the molecular system. The study of the quantum noises of these detectors highlights two exciting and technologically relevant directions for such devices : at room temperature these systems operate with levels of noise below state of the art devices, at lower temperatures these systems open an unexplored path towards single photon detection in a spectral range where this technology remains unavailable to date.

EPFL2020

Physics of optically driven nanojunctions

Philippe Andreas Rölli

EPFL2020