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Concept
Heterogeneous gold catalysis
Résumé
Heterogeneous gold catalysis refers to the use of elemental gold as a heterogeneous catalyst. As in most heterogeneous catalysis, the metal is typically supported on metal oxide. Furthermore, as seen in other heterogeneous catalysts, activity increases with a decreasing diameter of supported gold clusters. Several industrially relevant processes are also observed such as H2 activation, Water-gas shift reaction, and hydrogenation. No gold-catalyzed reaction has been commercialized.
The high activity of supported gold clusters has been proposed to arise from a combination of structural changes, quantum-size effects and support effects that preferentially tune the electronic structure of gold such that optimal binding of adsorbates during the catalytic cycle is enabled. The selectivity and activity of gold nanoparticles can be finely tuned by varying the choice of support material, with e.g. titania (TiO2), hematite (α-Fe2O3), cobalt(II/III) oxide (Co3O4) and nickel(II) oxide (NiO) serving as the most effective support materials for facilitating the catalysis of CO combustion. Besides enabling an optimal dispersion of the nanoclusters, the support materials have been suggested to promote catalysis by altering the size, shape, strain and charge state of the cluster. A precise shape control of the deposited gold clusters has been shown to be important for optimizing the catalytic activity, with hemispherical, few atomic layers thick nanoparticles generally exhibiting the most desirable catalytic properties due to maximized number of high-energy edge and corner sites.
In the past, heterogeneous gold catalysts have found commercial applications for the industrial production of polyvinyl chloride (PVC), methyl methacrylate, and catalytic converters. Traditionally, PVC production uses mercury catalysts and leads to serious environmental concerns. China accounts for 50% of world's mercury emissions and 60% of China's mercury emission is caused by PVC production. Although gold catalysts are slightly expensive, overall production cost is affected by only ~1%.
Source officielle
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