Fracture toughness of sandstone under dry, saturated and immerged conditions

Salma Lemghari
2020
Projet étudiant

Résumé

Water-induced strength reduction is one of the most critical causes of rock engineering disasters. Understanding the influence of water on the fracture toughness of rocks is necessary for rock fracture mechanics and rock engineering applications such as mining, tunneling, and the exploitation of deep geothermal reservoirs. However, only a few studies have been conducted to understand the effect of water on fracture properties such as fracture toughness. In this thesis, the effect of water on fracture toughness and fracture energy in several sandstones was investigated. First, several preliminary characterization tests were performed on all samples: P and S-wave velocity, porosity analysis, X-ray diffraction method, and thin section microscopic observation. CCNBD method was used to measure Mode I fracture toughness under dry, saturated and immerged conditions. Results show a decrease in fracture toughness and fracture energy after saturation and a higher decrease for immerged samples. The toughness reduction was larger for the most porous rocks and the one that contained a high percentage of phyllosilicates (clay minerals). We conclude that fracture toughness in sandstone is strongly affected by saturation, and mineralogy of the rock.

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https://infoscience.epfl.ch/record/273986?ln=fr

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Liquid lead-bismuth embrittlement effects on unirradiated and irradiated ferritic/martensitic steels for nuclear applications

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In liquid metal spallation targets such as the MEGAPIE (the megawatt pilot experiment) target and the future ADS (accelerator driven system) spallation targets, which utilize liquid lead-bismuth eutectic (LBE) as the target material, liquid metal embrittlement (LME) effects on the target structural materials are considered as one of the critical issues that determine the lifetime of the targets. However, nowadays, the LBE embrittlement effects are not yet well understood, particularly under irradiation conditions. The aim of this work was: (a) to investigate the effects of LBE embrittlement on the mechanical properties of ferritic-martensitic (FM) steels (candidate materials for applications in spallation targets) in various states, and (b) to study the mechanisms of LBE embrittlement effects on the mechanical properties of FM steels. These two goals have been reached by studying LBE embrittlement effects on the mechanical properties of the T91 steel in various conditions: (i) the standard normalized and tempered condition, (ii) hardened by tempering at lower temperatures, and (iii) after irradiation under high energy proton and spallation neutron mixed spectrum. Mechanical tests such as slow-strain-rate tensile (SSRT) tests and 3-point bending tests have been performed to characterize the mechanical properties of the T91 steel and to determine the effects of LBE embrittlement on these mechanical properties. Microstructural analyses such as transition electron microscopy (TEM) and scanning electron mirocopy (SEM) observations have been conducted to obtain the microstructural information needed for understanding the embrittlement mechanisms. SSRT tests on the T91 steel in the standard metallurgical (SM) state, tempered at 760°C and denoted as HT760, revealed that it may encounter LBE embrittlement in the temperature range of 300 to 425°C. For the first time, a well defined "ductility trough" for a FM steel – LBE system was evidenced from the reduction of the fracture strain (or total elongation) of the T91 FM steel in this temperature range. SEM observations of the fracture surfaces showed that the fracture mode of the specimens suffering embrittlement effects is brittle transgranular cleavage. SSRT tests on the hardened T91 steel, tempered at 500 or 600°C and denoted as HT500 and HT600, respectively, showed more pronounced LBE embrittlement effects. In comparison to that of HT760, the "ductility troughs" of HT600 and HT500 cover a wider temperature range. The LME onset temperature TE is not exactly known but most probably lower than 150°C, which means close to the melting point temperature (125°C) of LBE. The ductility recovery temperature TR of HT500 is higher than that of HT760 and HT600. The results of SSRT tests on the HT600 and HT500 materials demonstrate clearly that the LBE embrittlement effects on the tensile properties of FM steels are strongly enhanced by hardening. Both the influenced temperature range and the degradation level increase with the hardening amount. The fracture mode of HT600 and HT500 materials tested in liquid LBE at T ≤ 450°C showed mainly brittle transgranular cleavage. SSRT tests on the T91 and F82H FM steels irradiated at temperatures in the range of 140-500°C to doses in the range of 0.048 to 20 dpa revealed significant irradiation-induced hardening and embrittlement effects (loss of ductility) as compared to the unirradiated ones. The SSRT tests performed on irradiated specimens in liquid LBE revealed that the specimens undergo a further reduction in ductility. 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In liquid LBE the fracture toughness of FM steels can be reduced by about 20% as compared to that in inert Ar environment. 3-point bending tests on the hardened T91 materials HT500 and HT600 demonstrated that the LBE embrittlement effects are much more drastic for hardened materials, similarly to what was observed as a result from SSRT tests. The JQ value is reduced by as much as 95% for both HT600 and HT500 materials tested in liquid LBE. The hardened materials exhibit unstable crack propagation behavior in liquid LBE in a wide temperature range of 150 to 500°C. 3-point bending tests on the irradiated T91 steel revealed not only irradiation-induced embrittlement effects but also LBE embrittlement effects. The fracture toughness of the irradiated specimens was found to decrease further as a result from testing in liquid LBE. SEM observations of the fracture surface showed a mixture of intergranular and transgranular fracture. The LME phenomena evidenced for the T91 steel – LBE couple could be interpreted using the model of adsorption-induced reduction in cohesion of atomic bonds combined with the Kelly-Tyson-Cottrell (KTC) criterion (σ/τ ≥ σmax/τmax). According to the KTC criterion, the tendency to fail by cleavage increases as (σmax/τmax) decreases. The σmax value can be greatly reduced by adsorption of liquid Pb or Bi atoms at crack tips, while the τmax value can be increased by hardening the steel by means of either deformation, or tempering, or irradiation. Practically, the present results indicate that a great attention should be paid to application of FM steels in liquid LBE, since the mechanical properties of FM steels, such as the ductility and the fracture toughness, can be substantially degraded by LBE embrittlement effects, particularly under irradiation conditions as the LBE embrittlement are enhanced by irradiation-induced hardening. Fundamentally, the observations made in this work suggest that the mechanism responsible for liquid LBE-induced embrittlement effects on FM steels can be essentially interpreted by using the adsorption-induced reduction in cohesion of atomic bonds model combined with the KTC criterion for brittle cleavage fracture.

EPFL2009

Chargement

In this work we have studied brittle fracture in high-chromium reduced activation tempered martensitic steels foreseen as structural materials for thermonuclear fusion reactors. Developing the adequate materials that can withstand the severe irradiation conditions of the burning plasma in a future fusion reactor is one of the major challenges to be solved in order to make profit from the great advantages of thermonuclear fusion as an energy source. High-chromium tempered martensitic steels such as F82H and the most advanced version Eurofer97 are among the main candidate materials for structural applications in future fusion power plants due to low irradiation-induced swelling, good mechanical and thermal properties, and reasonably fast radioactive decay. The most concerning drawback of these kind of steels is irradiation embrittlement, which is manifested by a ductile-to-brittle transition temperature shift to higher temperatures after irradiation whose amplitude depends on the irradiation conditions (temperature, neutron flux, neutron fluence, etc). The aim of this work was to study and model brittle fracture in the ductile-brittle transition region of this kind of steels in the as-received unirradiated conditions. It is necessary to be able to transfer laboratory specimen fracture data to real components and structures in order to assess the performance of these steels in the different operating and transient conditions they could find during the operation life of a fusion reactor. In order to do so, the specimen geometry effects and specimen size effects on measured fracture toughness need to be properly understood, taken into account and predicted with an appropriate model. In particular, specimen size effect on measured toughness is a major concern for the nuclear materials research community owing to the limited irradiation volume in current and planed materials irradiation facilities. The main results of this PhD work are summarized below. The microstructure of Eurofer97 and F82H has been characterized and compared by means of optical microscopy, scanning electron microscopy, transmission electron microscopy and energy-dispersive X-ray spectroscopy in order to identify microstructural features that could play a role in the measured fracture toughness. Both steels have similar but slightly different chemical composition and final heat-treatments but the prior austenitic grain size measured in F82H is approximately 8 times larger than in Eurofer97. It was shown that the alloying element Tantalum, added to stabilize the austenite grain size, played a different role in both steels. After a careful analysis of the particles present in both steels, it was found that Tantalum in Eurofer97 formed carbides of an average size around 100 nanometers. In contrast in F82H it did not form small carbides but formed big oxide inclusions with a size up to 30 µm. These large particles do not effectively pin the grain boundaries. The different behavior of Tantalum in these steels is believed to be mainly a consequence of the larger content of Oxygen present and the smaller amount of Aluminum in F82H compared to Eurofer97. The Master-Curve ASTM-E1921 standard is a method initially developed to determine the ductile-to-brittle transition reference temperature, T0, in fission reactor ferritic steels from a small number of experiments. In this work the applicability of the Master-Curve method to reduced activation tempered martensitic steels such as Eurofer97 and F82H was studied in detail. Fracture tests with pre-cracked sub-sized compact tension specimens (three different sizes, 0.18T, 0.35T and 0.87T of Eurofer97) were carried out in the temperature range [-196 °C, -40 °C]. The toughness-temperature behavior and scatter were shown to deviate from the ASTM-E1921 standard predictions near the lower shelf. Using the method of maximum likelihood, the athermal component of the Master-Curve was calculated to better fit our fracture toughness data from the lower to the middle transition region. We showed that these Master-Curve adjustments are necessary to make the T0 values obtained near the lower shelf with 0.35T size C(T) specimens consistent with those obtained in the middle transition region with 0.87T C(T) specimens. The ASTM-E1921 specimen size limitations, setting the maximum toughness measurable with a given specimen size, were found to be too lenient for this kind of steels. This problem was especially evident in fracture toughness data of Eurofer97 and F82H obtained in the upper transition temperature range with two different specimen sizes. Thus a more stringent specimen size requirement was proposed to avoid inconsistent transition temperature determinations. A promising local fracture model with the potential of predicting cleavage fracture toughness was studied. Finite element simulations were undertaken for compact specimens, notched specimens and tensile specimens of Eurofer97 steel tested from 20 °C down to -197 °C. Three and two dimensional as well as axisymmetric simulations were run in order to calculate the stress and strain fields at the onset of brittle fracture. For each tested temperature, the calculated load-displacement curves were found to reproduce very well those of the experiments. A local approach fracture criterion was studied. 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Finally, the comparison between the overall fracture behavior in the transition between F82H and Eurofer97 steels indicated that these two materials are quite similar. A difference in the reference temperature T0 of about 20 °C was found, with a nominal value of -100 °C and -80 °C for F82H and Eurofer97 respectively. However, some excessive scatter in the toughness data was found in F82H with more data points than expected lying below the 1% tolerance bound; this was not observed in Eurofer97. From an engineering point of view, the entire fracture databases of these two steels are encompassed practically by the same lower tolerance bound.

EPFL2009

Chargement

Fracture and Fatigue of Adhesively-Bonded Fiber-Reinforced Polymer Structural Joints

Ye Zhang

Being good structural replacement for other conventional material, the pultruded glass fiber reinforced polymer (GFRP) profiles are being increasingly used in civil engineering structures. The connection between components is considered the most suspect area for failure initiation. The adhesive bonding is preferred for FRP composite structures, rather than the mechanical fastening, due to the brittle failure nature of composite materials. During past decades, many efforts have been made by researchers to better understand the mechanism of adhesive bonding, to analyze the stress distributions and to improve the strength of composite structural joints. However there is still no commonly accepted design code/standard existing for adhesively-bonded joints in civil engineering infrastructures since several important knowledge gaps are to be filled. Besides the joint strength at failure, the characterization and modeling of the progressive failure process, in particular involving the so-called crack initiation and propagation phases, is also an important concern. By employing the strain energy release rate (SERR) as the fracture parameter, the linear-elastic fracture mechanics (LEFM) approach is considered an efficient method to model the fracture behavior of structural joints. However, due to the uncontrollable crack initiation and the complex geometric configurations, the crack measurement techniques and the calculation method for the SERR are to be validated. In fracture mechanics, the fracture of a material or component can be described by a single mode or the combinations of the following three basic modes: opening mode (Mode I), shearing mode (Mode II), and tearing mode (Mode III). During the fracture of a structural joint, crack initiation and propagation are driven by combined through-thickness tensile (peeling), and shear stresses, thus resulting in a mixed mode fracture. In order to use the fracture results of structural joints to form the mixed fracture criterion for a specific composite material, a feasible analytical or numerical method are to be developed to determine the Mode I and II components of the SERR during fracture. Although many efforts have been made to better understand the short-term behavior of structural joint under quasi-static loading, the long-term performance under fatigue loading and different environmental conditions is a more demanding task when adhesively-bonded joints are applied in a real structure. Most of structural failures occur due to mechanisms that are driven by fatigue loading and for composite structures, the fatigue produced by the repeated application of live load is more critical due to its lighter self-weight, in other words the lower dead load. Besides the fatigue loading, a structure in practice may also experience the combined environmental effects of two basic factors: temperature and humidity. These environmental conditions may directly affect properties of structural joints, including the failure mechanism, the stiffness and strength, the crack initiation and propagation and etc.. Thus, the missing knowledge and confidences in the long-term behavior under cyclic loading and the durability under different environmental conditions are the main obstacles to the further development of FRP composites in civil engineering infrastructures. In this research, the mechanical and fracture behavior of adhesively-bonded double-lap and stepped-lap joints (DLJs and SLJs) composed of pultruded GFRP laminates and an epoxy adhesive were experimentally and numerically investigated under both quasi-static and fatigue loadings. The crack measurement techniques and the calculation methods for the SERR were validated for DLJs and SLJs. The LEFM approach was successfully applied to characterize and model the progressive failure process of structural joints. The Mode I and II components of the SERR of DLJs and SLJs were determined using the Virtual Crack Closure Technique in finite element analysis. Combining with the results of pure Mode I and II experiments, a mixed mode fracture criterion for pultruded GFRP composite was formed. Under fatigue loading, the fatigue behavior of structural joints was successfully modeled by using the stiffness-based and fracture mechanics approaches, besides the F-N curves. Based on the stiffness degradation, a linear and a sigmoid non-linear model were established and the fatigue live corresponding to the failure and allowable stiffness degradation can be predicted. Concerning fracture mechanics approach, the Fatigue Crack Growth (FCG) curves were formed for DLJs and SLJs and the corresponding fracture parameters were obtained. Similarly to stiffness-based approach, fatigue lives corresponding to the failure and allowable crack length can be predicted. The environmental effects on both short- and long-term performances of structural joints were experimentally evaluated and numerically modeled based on experimental results. The temperature-dependent joint stiffness can be predicted using the finite element analysis based on the thermomechanical properties of constituent materials. A relationship between the equivalent quasi-static joint strength under different environmental conditions and the cyclic stresses and the fatigue life was established.

EPFL2010

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Fracture and Fatigue of Adhesively-Bonded Fiber-Reinforced Polymer Structural Joints

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