Electrochemical promotion of ruthenium oxide catalysts for the gas phase combustion of ethylene
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The use of zeolites for catalytic reactions is a field in continuous development. Since it was demonstrated that metal-zeolites are efficient catalysts for NOx abatement, decomposition of nitrous oxide (N2O) over Fe-containing zeolites has attracted great ...
The current state of knowledge of cement hydration mechanisms is reviewed, including the origin of the period of slow reaction in alite and cement, the nature of the acceleration period, the role of calcium sulfate in modifying the reaction rate of tricalc ...
A combination of in situ time-resolved DXAFS and ICP-MS techniques reveals that the formation process of Rh nanoparticles (NPs) from rhodium trichloride trihydrate (RhCl3 center dot 3H(2)O) in ethylene glycol with polyvinylpyrrolidone (PVP) at elevated tem ...
Two different types of perturbations of an SCWR-like fuel lattice have been investigated experimentally in the central test zone of the PROTEUS zero-power research reactor at the Paul Scherrer Institute in Switzerland. In each case, a campaign of high-reso ...
Hierarchical zeolites are a class of microporous catalysts and adsorbents that also contain mesopores, which allow for fast transport of bulky molecules and thereby enable improved performance in petrochemical and biomass processing. We used repetitive bra ...
The substrate scope of the [2+2] cycloaddn.-cycloreversion (CA-CR) reaction between electron-deficient (2,2-dicyanovinyl)benzene (DCVB) or (1,2,2-tricyanovinyl)benzene (TCVB) derivs. and N,N-dimethylanilino (DMA)-substituted acetylenes was studied. The str ...
The electrochemical promotion of CO combustion over nano-dispersed Platinum particles supported on yttria stabilized zirconia (YSZ) is investigated at 300 degrees C under high vacuum conditions. By polarizing the nanoparticles, we were able to enhance the ...
The characterization of Fe/ZSM5 zeolite materials, the nature of Fe-sites active in N2O direct decomposition, as well as the rate limiting step are still a matter of debate. The mechanism of N2O decomposition on the binuclear oxo-hydroxo bridged extraframe ...
The Nazarov cyclization of divinyl ketones gives access to cyclopentenones. Replacing one of the vinyl groups by a cyclopropane leads to a formal homo-Nazarov process for the synthesis of cyclohexenones. In contrast to the Nazarov reaction, the cyclization ...
This work concerns the investigation of the electrochemical promotion of Pt/YSZ catalyst giving more emphasis to the sustainable enhanced catalytic activity after current interruption. The permanent electrochemical promotion (P-EPOC) of C2H4 combustion ove ...