The interpretation of photoemission-spectromicroscopy studies of Au on GaSe requires a revision of established ideas about this interface, which has long been considered a prototype of Schottky-like systems. We find that the interface-formation process involves strong substrate-overlayer interactions, the release of free Ga, and the formation of interface species, and leads to a barrier height in total disagreement with the Schottky model. Furthermore, the space-resolving capabilities of our instruments revealed lateral inhomogeneities of the local overlayer thickness and of the local band bending.
Xiao Zhou, Cheng Chen, Pengfei Ou
Elison de Nazareth Matioli, Luca Nela, Catherine Erine