Carbon fibre reinforced carbon (CFRC),
carbon–carbon (C/C),
or reinforced carbon–carbon (RCC)
is a composite material consisting of carbon fiber reinforcement in a matrix of graphite. It was developed for the reentry vehicles of intercontinental ballistic missiles, and is most widely known as the material for the nose cone and wing leading edges of the Space Shuttle orbiter. Carbon-carbon brake discs and brake pads have been the standard component of the brake systems of Formula One racing cars since the late 1970s; the first year carbon brakes were seen on a Formula One car was 1976.
Carbon–carbon is well-suited to structural applications at high temperatures, or where thermal shock resistance and/or a low coefficient of thermal expansion is needed. While it is less brittle than many other ceramics, it lacks impact resistance; Space Shuttle Columbia was destroyed during atmospheric re-entry after one of its RCC panels was broken by the impact of a piece of polyurethane foam insulation that broke off from the Space Shuttle External Tank.
The material is made in three stages:
First, material is laid up in its intended final shape, with carbon filament and/or cloth surrounded by an organic binder such as plastic or pitch. Often, coke or some other fine carbon aggregate is added to the binder mixture.
Second, the lay-up is heated, so that pyrolysis transforms the binder to relatively pure carbon. The binder loses volume in the process, causing voids to form; the addition of aggregate reduces this problem, but does not eliminate it.
Third, the voids are gradually filled by forcing a carbon-forming gas such as acetylene through the material at a high temperature, over the course of several days. This long heat treatment process also allows the carbon to form into larger graphite crystals, and is the major reason for the material's high cost. The gray "Reinforced Carbon–Carbon (RCC)" panels on the space shuttle's wing leading edges and nose cone cost NASA $100,000/sq ft to produce, although much of this cost was a result of the advanced geometry and research costs associated with the panels.
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