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Concept
Rotating disk electrode
Summary
In analytical chemistry, a rotating disk electrode (RDE) is a working electrode used in three-electrode systems for hydrodynamic voltammetry. The electrode rotates during experiments, inducing a flux of analyte to the electrode. These working electrodes are used in electrochemical studies when investigating reaction mechanisms related to redox chemistry, among other chemical phenomena. The more complex rotating ring-disk electrode can be used as a rotating disk electrode if the ring is left inactive during the experiment.
The electrode includes a conductive disk embedded in an inert non-conductive polymer or resin that can be attached to an electric motor that has very fine control of the electrode's rotation rate. The disk, like any working electrode, is generally made of a noble metal or glassy carbon, however any conductive material can be used based on specific needs.
The disk's rotation is usually described in terms of angular velocity. As the disk turns, some of the solution described as the hydrodynamic boundary layer is dragged by the spinning disk and the resulting centrifugal force flings the solution away from the center of the electrode. Solution flows up, perpendicular to the electrode, from the bulk to replace the boundary layer. The sum result is a laminar flow of solution towards and across the electrode. The rate of the solution flow can be controlled by the electrode's angular velocity and modeled mathematically. This flow can quickly achieve conditions in which the steady-state current is controlled by the solution flow rather than diffusion. This is a contrast to still and unstirred experiments such as cyclic voltammetry where the steady-state current is limited by the diffusion of species in solution.
By running linear sweep voltammetry and other experiments at various rotation rates, different electrochemical phenomena can be investigated, including multi-electron transfer, the kinetics of a slow electron transfer, adsorption/desorption steps, and electrochemical reaction mechanisms.
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