A colloidal crystal is an ordered array of colloidal particles and fine grained materials analogous to a standard crystal whose repeating subunits are atoms or molecules. A natural example of this phenomenon can be found in the gem opal, where spheres of silica assume a close-packed locally periodic structure under moderate compression. Bulk properties of a colloidal crystal depend on composition, particle size, packing arrangement, and degree of regularity. Applications include photonics, materials processing, and the study of self-assembly and phase transitions.
A colloidal crystal is a highly ordered array of particles which can be formed over a long range (to about a centimeter). Arrays such as this appear to be analogous to their atomic or molecular counterparts with proper scaling considerations. A good natural example of this phenomenon can be found in precious opal, where brilliant regions of pure spectral color result from close-packed domains of colloidal spheres of amorphous silicon dioxide, SiO2 (see above illustration). The spherical particles precipitate in highly siliceous pools and form highly ordered arrays after years of sedimentation and compression under hydrostatic and gravitational forces. The periodic arrays of spherical particles make similar arrays of interstitial voids, which act as a natural diffraction grating for light waves in photonic crystals, especially when the interstitial spacing is of the same order of magnitude as the incident lightwave.
The origins of colloidal crystals go back to the mechanical properties of bentonite sols, and the optical properties of Schiller layers in iron oxide sols. The properties are supposed to be due to the ordering of monodisperse inorganic particles. Monodisperse colloids, capable of forming long-range ordered arrays, existing in nature. The discovery by W.M. Stanley of the crystalline forms of the tobacco and tomato viruses provided examples of this.
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The course covers the production of ceramics and colloids from the basic scientific concepts and theories needed to understand the forming processes to the mechanisms and methods of sintering (firing)
The first part of the course is devoted to the self-assembly of molecules. In the second part we discuss basic physical chemical principles of polymers in solutions, at interfaces, and in bulk. Finall
Students analyze crystal structures, point defects and phase relations in ceramic materials and understand their effect on electrical, thermal and electromechanical properties. Properties of ceramic m
Particle agglomeration refers to the formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglomerates. This phenomenon is also referred to as coagulation or flocculation and such a suspension is also called unstable. Particle agglomeration can be induced by adding salts or other chemicals referred to as coagulant or flocculant.
Ceramic engineering is the science and technology of creating objects from inorganic, non-metallic materials. This is done either by the action of heat, or at lower temperatures using precipitation reactions from high-purity chemical solutions. The term includes the purification of raw materials, the study and production of the chemical compounds concerned, their formation into components and the study of their structure, composition and properties. Ceramic materials may have a crystalline or partly crystalline structure, with long-range order on atomic scale.
In materials science, the sol–gel process is a method for producing solid materials from small molecules. The method is used for the fabrication of metal oxides, especially the oxides of silicon (Si) and titanium (Ti). The process involves conversion of monomers into a colloidal solution (sol) that acts as the precursor for an integrated network (or gel) of either discrete particles or network polymers. Typical precursors are metal alkoxides. Sol-gel process is used to produce ceramic nanoparticles.
Explores ceramic powder transformation through fragmentation operations, particle rupture mechanisms, and interparticle forces like van der Waals forces.
Colloid particle size plays an important role in contaminant adsorption and clogging in the hyporheic zone, but it remains unclear how the particle size changes during the transport of colloids. This study investigated the variation of the particle size of ...
In aqueous solutions, a charged surface causes the redistribution of nearby ions. The ion layers formed are known as the electrical double layer (EDL), and are widespread in many systems involving electrochemistry, colloidal science, biomedicine, and energ ...
Biominerals are used by natural organisms for example as structural supports and optical sensors. They are produced from a limited number of elements and under ambient conditions. Nevertheless, they often possess excellent mechanical properties and sometim ...