In engineering, applied mathematics, and physics, the Buckingham pi theorem is a key theorem in dimensional analysis. It is a formalization of Rayleigh's method of dimensional analysis. Loosely, the theorem states that if there is a physically meaningful equation involving a certain number n of physical variables, then the original equation can be rewritten in terms of a set of p = n − k dimensionless parameters pi1, pi2, ..., pip constructed from the original variables, where k is the number of physical dimensions involved; it is obtained as the rank of a particular matrix.
The theorem provides a method for computing sets of dimensionless parameters from the given variables, or nondimensionalization, even if the form of the equation is still unknown.
The Buckingham pi theorem indicates that validity of the laws of physics does not depend on a specific unit system. A statement of this theorem is that any physical law can be expressed as an identity involving only dimensionless combinations (ratios or products) of the variables linked by the law (for example, pressure and volume are linked by Boyle's law – they are inversely proportional). If the dimensionless combinations' values changed with the systems of units, then the equation would not be an identity, and the theorem would not hold.
Although named for Edgar Buckingham, the pi theorem was first proved by the French mathematician Joseph Bertrand in 1878. Bertrand considered only special cases of problems from electrodynamics and heat conduction, but his article contains, in distinct terms, all the basic ideas of the modern proof of the theorem and clearly indicates the theorem's utility for modelling physical phenomena. The technique of using the theorem ("the method of dimensions") became widely known due to the works of Rayleigh. The first application of the pi theorem in the general case to the dependence of pressure drop in a pipe upon governing parameters probably dates back to 1892, a heuristic proof with the use of series expansions, to 1894.
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