In optics, a dispersive prism is an optical prism that is used to disperse light, that is, to separate light into its spectral components (the colors of the rainbow). Different wavelengths (colors) of light will be deflected by the prism at different angles. This is a result of the prism material's index of refraction varying with wavelength (dispersion). Generally, longer wavelengths (red) undergo a smaller deviation than shorter wavelengths (blue). The dispersion of white light into colors by a prism led Sir Isaac Newton to conclude that white light consisted of a mixture of different colors.
Triangular prisms are the most common type of dispersive prism. Other types of dispersive prism exist that have more than two optical interfaces; some of them combine refraction with total internal reflection.
Light changes speed as it moves from one medium to another (for example, from air into the glass of the prism). This speed change causes the light to be refracted and to enter the new medium at a different angle (Huygens principle). The degree of bending of the light's path depends on the angle that the incident beam of light makes with the surface, and on the ratio between the refractive indices of the two media (Snell's law). The refractive index of many materials (such as glass) varies with the wavelength or color of the light used, a phenomenon known as dispersion. This causes light of different colors to be refracted differently and to leave the prism at different angles, creating an effect similar to a rainbow. This can be used to separate a beam of white light into its constituent spectrum of colors.
Prisms will generally disperse light over a much larger frequency bandwidth than diffraction gratings, making them useful for broad-spectrum spectroscopy. Furthermore, prisms do not suffer from complications arising from overlapping spectral orders, which all gratings have. A usual disadvantage of prisms is lower dispersion than a well-chosen grating can achieve.
Prisms are sometimes used for the internal reflection at the surfaces rather than for dispersion.
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