Summary
In group theory, a branch of abstract algebra, a character table is a two-dimensional table whose rows correspond to irreducible representations, and whose columns correspond to conjugacy classes of group elements. The entries consist of characters, the traces of the matrices representing group elements of the column's class in the given row's group representation. In chemistry, crystallography, and spectroscopy, character tables of point groups are used to classify e.g. molecular vibrations according to their symmetry, and to predict whether a transition between two states is forbidden for symmetry reasons. Many university level textbooks on physical chemistry, quantum chemistry, spectroscopy and inorganic chemistry devote a chapter to the use of symmetry group character tables. The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a compact form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions). The columns are labelled by (representatives of) the conjugacy classes of G. It is customary to label the first row by the character of the trivial representation, which is the trivial action of G on a 1-dimensional vector space by for all . Each entry in the first row is therefore 1. Similarly, it is customary to label the first column by the identity. The entries of the first column are the values of the irreducible characters at the identity, the degrees of the irreducible characters. Characters of degree 1 are known as linear characters. Here is the character table of C3 = , the cyclic group with three elements and generator u: where ω is a primitive third root of unity. The character table for general cyclic groups is (a scalar multiple of) the DFT matrix. Another example is the character table of : where (12) represents conjugacy class consisting of (12),(13),(23), and (123) represents conjugacy class consisting of (123),(132).
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