Highly Active and Stable Iridium Pyrochlores for Oxygen Evolution Reaction
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Computer simulations based on statistical methods have emerged as a powerful tool for studying structure-property relationships at the atomistic level. However, to provide reliable insights into materials in realistic conditions, it is essential to accurat ...
The need for efficient and selective catalysts, capable of driving important conversions to build a more sustainable society, encourages the development of synthetic approaches towards new nanomaterials. Cu-based bimetallic nanoparticles (NPs) promise to f ...
Group 9 metals, in particular Rh III complexes with cyclopentadienyl ligands, are competent C–H activation catalysts. Recently, a Cp*Rh III catalyzed reaction of alkenes with N -enoxyphthalimides showed divergent outcome based on the solvent, with carboami ...
The application of Earth-abundant metals in asymmetric catalysis is key to transition towards a more sustainable chemistry. In particular, expanding the library of redox-active ligands capable of supporting Earth-abundant metals is essential in order to re ...
EPFL2022
In the last decades, the femtosecond laser micromachining of glass has attracted a lot of attention due to its three-dimensional manufacturing ability and flexibility both in terms of compatible substrates and modification types. Yet, to fully unravel its ...
EPFL2022
The generation of catalyst design tools is important for developing both economically and environmentally friendly reactions. This thesis focuses on the use and development of such a tool, molecular volcano plots, which have the ability to estimate catalyt ...
EPFL2021
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Despite remarkable progress made in recent years, producing freeform three-dimensional micro-components out of copper, silver or gold and their alloys remains an engineering challenge: current processes are either too slow to be economically viable, or pro ...
2021
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Nowadays, molybdenum carbides (Mo2C) represent alternative electrocatalysts to noble metal for the hydrogen evolution reaction (HER). Here, a fast and simple process is proposed for the fabrication of Mo2C-based electrocatalysts on a carbon cloth substrate ...
AMER CHEMICAL SOC2021
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Due to the highly complex polyphenolic structure of lignin, depolymerization without a prior chemical treatment is challenging, and new catalysts are required. Atomically dispersed catalysts are able to maximize the atomic efficiency of noble metals, simul ...
ELSEVIER2021
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Plasmonic nanojunctions, consisting of adjacent metal structures with nanometre gaps, can support localised plasmon resonances that boost light matter interactions and concentrate electromagnetic fields at the nanoscale. In this regime, the optical respons ...
