Homotopy categoryIn mathematics, the homotopy category is a built from the category of topological spaces which in a sense identifies two spaces that have the same shape. The phrase is in fact used for two different (but related) categories, as discussed below. More generally, instead of starting with the category of topological spaces, one may start with any and define its associated homotopy category, with a construction introduced by Quillen in 1967. In this way, homotopy theory can be applied to many other categories in geometry and algebra.
Selection ruleIn physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in atomic nuclei, and so on. The selection rules may differ according to the technique used to observe the transition. The selection rule also plays a role in chemical reactions, where some are formally spin-forbidden reactions, that is, reactions where the spin state changes at least once from reactants to products.
Bousfield localizationIn , a branch of mathematics, a (left) Bousfield localization of a replaces the model structure with another model structure with the same cofibrations but with more weak equivalences. Bousfield localization is named after Aldridge Bousfield, who first introduced this technique in the context of localization of topological spaces and spectra. Given a class C of morphisms in a M the left Bousfield localization is a new model structure on the same category as before.
Infrared spectroscopyInfrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum.
HomotopyIn topology, a branch of mathematics, two continuous functions from one topological space to another are called homotopic (from ὁμός "same, similar" and τόπος "place") if one can be "continuously deformed" into the other, such a deformation being called a homotopy (həˈmɒtəpiː, ; ˈhoʊmoʊˌtoʊpiː, ) between the two functions. A notable use of homotopy is the definition of homotopy groups and cohomotopy groups, important invariants in algebraic topology. In practice, there are technical difficulties in using homotopies with certain spaces.
Homotopy colimit and limitIn mathematics, especially in algebraic topology, the homotopy limit and colimitpg 52 are variants of the notions of and colimit extended to the homotopy category . The main idea is this: if we have a diagramconsidered as an object in the , (where the homotopy equivalence of diagrams is considered pointwise), then the homotopy limit and colimits then correspond to the and coconewhich are objects in the homotopy category , where is the category with one object and one morphism.
Rotational spectroscopyRotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase. The spectra of polar molecules can be measured in absorption or emission by microwave spectroscopy or by far infrared spectroscopy. The rotational spectra of non-polar molecules cannot be observed by those methods, but can be observed and measured by Raman spectroscopy.
Rotational–vibrational spectroscopyRotational–vibrational spectroscopy is a branch of molecular spectroscopy concerned with infrared and Raman spectra of molecules in the gas phase. Transitions involving changes in both vibrational and rotational states can be abbreviated as rovibrational (or ro-vibrational) transitions. When such transitions emit or absorb photons (electromagnetic radiation), the frequency is proportional to the difference in energy levels and can be detected by certain kinds of spectroscopy.
Spectrum (topology)In algebraic topology, a branch of mathematics, a spectrum is an object representing a generalized cohomology theory. Every such cohomology theory is representable, as follows from Brown's representability theorem. This means that, given a cohomology theory,there exist spaces such that evaluating the cohomology theory in degree on a space is equivalent to computing the homotopy classes of maps to the space , that is.Note there are several different of spectra leading to many technical difficulties, but they all determine the same , known as the stable homotopy category.
Homotopy type theoryIn mathematical logic and computer science, homotopy type theory (HoTT hɒt) refers to various lines of development of intuitionistic type theory, based on the interpretation of types as objects to which the intuition of (abstract) homotopy theory applies. This includes, among other lines of work, the construction of homotopical and models for such type theories; the use of type theory as a logic (or internal language) for abstract homotopy theory and ; the development of mathematics within a type-theoretic foundation (including both previously existing mathematics and new mathematics that homotopical types make possible); and the formalization of each of these in computer proof assistants.